Belokon's Ni(II) complex as a chiral masked glycine for the diastereoselective synthesis of 2-substituted 1-aminocyclopropane carboxylic acids
مقال من تأليف: Debache, Abdelmadjid ; Collet, Sylvain ; Bauchat, Patrick ; Danion, Daniel ; Euzenat, Lisenn ; Hercouet, Alain ; Carboni, Bertrand ;
ملخص: (1S,2R)- and (1R,2S)-Allonorcoronamic acids have been efficiently synthesised from the cyclic sulfate of 1,2-propanediol and Belokon's complex (a complex of Ni(II) with glycine-(S)-2-[N′-(N-benzylprolyl)amino]benzophenone Schiff base ligands). The stereochemical outcome of the reaction was totally controlled by the sulfate partner.
لغة:
إنجليزية