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تفاصيل البطاقة الفهرسية

Synthesis of indenone by self-condensation of 1-acetyl-2-methylcyclopentene and subsequent unusual autoxidation

مقال من تأليف: Miloudi, Abdellah ; El Abed, Douniazad ; Pons, Jean-Marc ; Santelli, Maurice ;

ملخص: Potassium tert-butoxide induced self-condensation of 1-acetyl-2-methyl-cyclopentene leads to 6-methyl-4-(2′-methylcyclopent-1′-enyl)bicyclo[4.3.0]non-3-en-2-one 2 in 35% yield when one equivalent of dimethyl sulfate is added. Dienone 2 undergoes facile autoxidation leading to the corresponding epoxide 12 and triketone 13.


لغة: إنجليزية