ملخص: It is well known that lead dioxide contains, what has been called, ‘structural water’. Present in the form of OH- ions replacing O2- ions in the anionic sublattice, the ‘structurally bonded’ water can be removed by heating, in the temperature range from 150 to 250 [deg]C. In the present study, the discharge capacities of fresh and heat-treated (140 and 230 [deg]C, respectively) [alpha]- and [beta]-PbO2 samples were evaluated in H2SO4 solution of 1.28 g cm-3 sp. gr. at different current densities of 5 to 40 mA cm-2. It was found that the capacity decreased when structural water was removed. This loss of capacity is important when [alpha]-PbO2 samples are considered. The energy of dehydroxilation was deduced by applying kinetic considerations to thermograms, obtained experimentally. The removal of the OH- groups from [beta]-PbO2 needs an energy twice that of the [alpha]-form.

لغة: إنجليزية